Mark Greenhalgh
Mark Greenhalgh
Assistant Professor, University of Warwick
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Iron‐catalysed hydrofunctionalisation of alkenes and alkynes
MD Greenhalgh, AS Jones, SP Thomas
ChemCatChem 7 (2), 190-222, 2015
Iron-Catalyzed, Highly Regioselective Synthesis of α-Aryl Carboxylic Acids from Styrene Derivatives and CO2
MD Greenhalgh, SP Thomas
Journal of the American Chemical Society 134 (29), 11900-11903, 2012
Chemo-, regio-, and stereoselective iron-catalysed hydroboration of alkenes and alkynes
MD Greenhalgh, SP Thomas
Chemical Communications 49 (95), 11230-11232, 2013
Iron‐catalysed chemo‐, regio‐, and stereoselective hydrosilylation of alkenes and alkynes using a bench‐stable iron (II) pre‐catalyst
MD Greenhalgh, DJ Frank, SP Thomas
Advanced Synthesis & Catalysis 356 (2‐3), 584-590, 2014
Non-bonding 1, 5-S⋯ O interactions govern chemo-and enantioselectivity in isothiourea-catalyzed annulations of benzazoles
ERT Robinson, DM Walden, C Fallan, MD Greenhalgh, PHY Cheong, ...
Chemical Science 7 (12), 6919-6927, 2016
AC= O⋅⋅⋅ Isothiouronium Interaction Dictates Enantiodiscrimination in Acylative Kinetic Resolutions of Tertiary Heterocyclic Alcohols
MD Greenhalgh, SM Smith, DM Walden, JE Taylor, Z Brice, ...
Angewandte Chemie 130 (12), 3254-3260, 2018
Best practice considerations for using the selectivity factor, s, as a metric for the efficiency of kinetic resolutions
MD Greenhalgh, JE Taylor, AD Smith
Tetrahedron 74 (38), 5554-5560, 2018
Aryloxide‐Facilitated Catalyst Turnover in Enantioselective α, β‐Unsaturated Acyl Ammonium Catalysis
A Matviitsuk, MD Greenhalgh, DJB Antúnez, AMZ Slawin, AD Smith
Angewandte Chemie 129 (40), 12450-12455, 2017
Acylative kinetic resolution of alcohols using a recyclable polymer-supported isothiourea catalyst in batch and flow
RM Neyyappadath, R Chisholm, MD Greenhalgh, C Rodríguez-Escrich, ...
ACS Catalysis 8 (2), 1067-1075, 2018
Iron-catalyzed hydromagnesiation: synthesis and characterization of benzylic Grignard reagent intermediate and application in the synthesis of ibuprofen
MD Greenhalgh, A Kolodziej, F Sinclair, SP Thomas
Organometallics 33 (20), 5811-5819, 2014
Broad scope hydrofunctionalization of styrene derivatives using iron-catalyzed hydromagnesiation
AS Jones, JF Paliga, MD Greenhalgh, JM Quibell, A Steven, SP Thomas
Organic letters 16 (22), 5964-5967, 2014
Isothiourea‐Catalyzed Acylative Kinetic Resolution of Tertiary α‐Hydroxy Esters
S Qu, SM Smith, V Laina‐Martín, RM Neyyappadath, MD Greenhalgh, ...
Angewandte Chemie International Edition 59 (38), 16572-16578, 2020
Catalytic enantioselective synthesis of perfluoroalkyl-substituted β-lactones via a concerted asynchronous [2+ 2] cycloaddition: a synthetic and computational study
DJB Antúnez, MD Greenhalgh, AC Brueckner, DM Walden, ...
Chemical Science 10 (24), 6162-6173, 2019
Isothiourea‐catalysed regioselective acylative kinetic resolution of axially chiral biaryl diols
S Qu, MD Greenhalgh, AD Smith
Chemistry–A European Journal 25 (11), 2816-2823, 2019
Multiple roles of aryloxide leaving groups in enantioselective annulations employing α, β-unsaturated acyl ammonium catalysis
MD Greenhalgh, S Qu, AMZ Slawin, AD Smith
Chemical Science 9 (21), 4909-4918, 2018
Evaluating polymer-supported isothiourea catalysis in industrially-preferable solvents for the acylative kinetic resolution of secondary and tertiary heterocyclic alcohols in …
NR Guha, RM Neyyappadath, MD Greenhalgh, R Chisholm, SM Smith, ...
Green Chemistry 20 (19), 4537-4546, 2018
Iron-catalysed, hydride-mediated reductive cross-coupling of vinyl halides and Grignard reagents
BAF Le Bailly, MD Greenhalgh, SP Thomas
Chemical Communications 48 (10), 1580-1582, 2012
Iron-Catalyzed Hydromagnesiation of Olefins
MD Greenhalgh, SP Thomas
Synlett 24 (05), 531-534, 2013
Mechanism of the bis (imino) pyridine-iron-catalyzed hydromagnesiation of styrene derivatives
PGN Neate, MD Greenhalgh, WW Brennessel, SP Thomas, ML Neidig
Journal of the American Chemical Society 141 (25), 10099-10108, 2019
Tandem sequential catalytic enantioselective synthesis of highly-functionalised tetrahydroindolizine derivatives
S Zhang, MD Greenhalgh, AMZ Slawin, AD Smith
Chemical Science 11 (15), 3885-3892, 2020
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